Not really. If you counter the accelerant, he has 2 mana in his pool and 3 cards in hand. To win from this situation, he needs those 3 cards to consist of 2 accelerants and EtW. If those are the cards he has in hand, he wins regardless of which spell you counter. But if he only has 1 accelerant, he fizzles. Or, if has a Wish or a Belcher instead of EtW, he fizzles for the turn. By countering that accelerant, you have the greatest chance of stopping the combo.
As described above, this isn't true (unless you have an answer to EtW).
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